Product ID:DEVELOPER FLUID CONTAINED IN POD OF FILM (SUPDAT)
MSDS Date:10/08/1993
FSC:6850
NIIN:00N066759
MSDS Number: BZMRR

POLAROID CORP

1265 MAIN ST
WALTHAM, MA 02254
US

Emergency Phone: 617-386-0879

Info Phone: 617-386-0879

Preparer: E. KARGER

Cage: 0E411

POLAROID CORP, HEALTH, SAFETY & ENVIRONMENT

WALTHAM, MA 02254 US

Telephone: 617-684-3646

Cage: 9C354

POTASSIUM HYDROXIDE (CERCLA)

CAS: 1310-58-3

RTECS: TT2100000

Fraction By Weight: 1-5%

OSHA PEL 2 MG/M3, C

ACGIH TLV: 2 MG/M3, C

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LITHIUM HYDROXIDE; (LITHIUM HYDROXIDE MONOHYDRATE)

CAS: 1310-65-2

RTECS: OJ6307070

Fraction By Weight: 1-5%

OSHA PEL N/K

ACGIH TLV: N/K

HYDROQUINONE, TERT-BUTYL-; (T-BUTYLHYDROQUINONE)

CAS: 1948-33-0

RTECS: MX4375000

Fraction By Weight: 1-5%

OSHA PEL N/K

ACGIH TLV: N/K

SODIUM SULFITE; (SODIUM SULFITE ANHYDROUS)

CAS: 7757-83-7

RTECS: WE2150000

Fraction By Weight: 1-5%

OSHA PEL N/K

ACGIH TLV: N/K

1); (SODIUM THIOSULFATE PENTAHYDRATE)

CAS: 10102-17-7

RTECS: WE6660000

Fraction By Weight: 5-10%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CORROSIVE. INHALATION: MAY BE AN
IRRITANT. EYE CONTACT WITH DEVELOPER MAY CAUSE PERMANENT EYE
DAMAGE. SKIN/INGESTION: MAY CAUSE BURNS TO SKIN AND MOUTH.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN; SEEK
MED ATTN. SKIN: FLUSH AFFECTED AREA W/PLENTY OF WATER. INGEST:
RINSE MOUTH IMMED W/PLENTY OF WATER. DRINK WATER/CITRUS JUICE TO
DILUTE OR N EUTRALIZE ANY ALKALI THAT MAY HAVE BEENSWALLOWED. DO
NOT INDUCE VOMIT. SEEK MED ATTN IMMED. INGEST: SEEK MED ATTN IMMED.
DO NOT INDUCE VOMIT. NOTE TO MD: PRLNGD CNTCT W/SKIN MAY PRDCE
ALKALI BURNS.

Flash Point Method:TCC
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:MIXTURE WILL NOT BURN.

Spill Release Procedures:HANDLE FILM SO AS NOT TO BREAK DEVELOPER PODS
PRIOR TO FILM DEVELOPMENT. SMALL QUANTITIES OF DEVELOPER FLUID MAY
BE WIPED UP WITH A DAMP PAPER TOWEL USING CARE TO AVOID ANY SKIN OR
EYE CONTACT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT GET IN EYES, ON SKIN, MOUTH OR
CLOTHING.
Other Precautions:NOTE: FILM CONFORMS TO ASTM D-4236.

Respiratory Protection:NOT NORMALLY REQUIRED. USE NIOSH/MSHA APPROVED
RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:NOT NORMALLY REQUIRED. PROCESSING OF LARGE QUANTITIES OF
FILM SHOULD BE HANDLED WITH LOCAL EXHAUST VENTILATION.
Protective Gloves:NEOPRENE/NITRILE/BUTYL RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (SUPDAT)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO: TYPES 665, 105, 55. PH: >13 - DROPS RAPIDLY
AFTER PROCESSING. EYE PROT: & FULL LENGTH FACESHIELD .

Boiling Pt:B.P. Text:212F,100C
Spec Gravity:1.1 (H*2O=1)
pH:SUPDAT
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:DILUTABLE @ 20C
Appearance and Odor:CREAM, WHITE, TAN, GREY OR PINK VISCOUS FLUID.
Percent Volatiles by Volume:85

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS . PRODUCT (FILM PACK, POSITIVE AND
NEGATIVE) IS NOT CLASSIFIED OR REGULATED UNDER U.S. FEDERAL LAW AS
"RCRA HAZARDOUS" BE FORE OR AFTER PROCESSING.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.